Along with the observed high conversions, the SAC and NaBH4 combination also exhibits a selectively catalyzed reduction in compounds containing other reducible functionalities, such as CN, Br, Cl and I. %PDF-1.4 %���� 21 0 obj <> endobj xref 21 19 0000000016 00000 n 0000008321 00000 n ^O�w�q�����%�8O�^�n���N;�}:&�T�tu�Wm���-K������vm������ͮ;�_�{�{��[ �]k�>k���E��6�3߫`�hȖ�{W�;��ļ��2?�}���[���rܷU���+U��)~\} �)������s�v84�P����`RR����p���-�ts�Y����� HR..H. A simple and general homogeneous catalyst system composed of commercially available [Ir(cod)Cl]2 and 1,10-phenanthroline has been developed for the selective transfer hydrogenation of nitroarenes to anilines. 0000034801 00000 n 0000043004 00000 n 0000036681 00000 n Reduction of aromatic nitro compounds with Raney nickel catalyst Download PDF Info Publication number US4287365A. 58 0 obj <> endobj 0000003665 00000 n <>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]>>/Parent 34 0 R/MediaBox[0 0 595.32 841.92]/Contents 41 0 R/Type/Page>> ChemInform Abstract: Selective Hydrogenation of Nitroaromatic Compounds with a Nickel-Oxide-Supported Nano-Palladium Catalyst under Ambient Reaction Conditions. In addition, CYP450 and hERG assays presented a safe toxicity profile of 20. materials is investigated for reduction of nitrobenzene. Herein, we report quinazoline based compounds with potent cytotoxic activities against brain cancer cell lines. 0000044069 00000 n <>/Length 15410>>stream 0000001877 00000 n 32 0 obj 0000000853 00000 n %PDF-1.4 %���� 0000040806 00000 n 28 15.10: Spectroscopy of Aromatic Compounds IR: Aromatic ring C–H stretching at 3030 cm−1 and 0000049648 00000 n Synthesis of novel TSPO antagonists with antiproliferative activity against brain cancer, based on a new access to quinazoline, One-pot synthesis of Ni–NiFe2O4/carbon nanofiber composites from biomass for selective hydrogenation of aromatic nitro compounds, Swift and Selective Reduction of Nitroaromatics to Aromatic Amines with Ni–Boride–Silica Catalysts System at Low Temperature, On the surface reactions during NO reduction with propene and propane on Ni-exchanged mordenite. <>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]>>/Parent 34 0 R/MediaBox[0 0 595.32 841.92]/Contents 35 0 R/Type/Page>> h�b```g``�����`��A��X��,SDL���1����XA� �EG .�s�Iff(v��s�,���h�� �4ThӸ��خ0�[�#��PP. 36 0 obj 0000002008 00000 n 0000044330 00000 n endobj 29 HYDROGENATION OF AROMATIC NITRO -COMPOUNDS Bè)Ð6 ÖCdCbCy { ' B1 Ó& {Bé N O 2 O 3 N H 2 O-Nitroacetophenone 3 -CdCbCyCOC\CbCjCHCgC{ Bè3 -CdCbCyCjCHCdCwCRC^CgC{Bé 3 Aminoacetophenone 3 0000044119 00000 n 0000028345 00000 n 0000017956 00000 n endobj 0000001667 00000 n 0000025747 00000 n 0000039294 00000 n 0000017374 00000 n 0000001270 00000 n 0000000016 00000 n 0000017692 00000 n Ni–NiFe2O4/carbon nanofiber (Ni–NiFe2O4/CNF) composite materials were synthesized by fast pyrolysis of the FeCl3 and NiCl2 preloaded biomass. 0000038278 00000 n endobj 0000031177 00000 n 0000001786 00000 n 85 45 2 0 obj startxref Effect of catalyst and substituents on the hydrogenation of chloronitrobenzenes, Comparative Study of Homogeneous and Silica Immobilized N^N and N^O Palladium(II) Complexes as Catalysts for Hydrogenation of Alkenes, Alkynes and Functionalized Benzenes, Biotransformation, toxicity and remediation of aromatic nitro compound explosives, Effect of reduction in liquid phase on the properties and the catalytic activity of Pd/Al2O3 catalysts, Highly Efficient Ultra-low Loading Pd Supported on MAX Phases for Chemoselective Hydrogenation, Three consecutive steps over the chirally modified Pt surface: Asymmetric catalytic cascade reaction of 2-nitrophenylpyruvates, General and Selective Reductive Amination of Carbonyl Compounds Using a Core-Shell Structured Co/Co3O4@C-Nx Catalyst. 85 0 obj<> endobj <>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]>>/Parent 3 0 R/MediaBox[0 0 595.32 841.92]/Contents 7 0 R/Type/Page>> xref 0000016390 00000 n Various nitroaromatics are successfully reduced to amines with 100% conversion and selectivity in methanol at low temperature 0000044355 00000 n 0000016279 00000 n 0000001256 00000 n x��!�A�|�)��e�suEP~ֱ֤��a�oW"��d�\��"*��n�N�>��F���!s�t0�]2frS�m3�D8�u�O�È�)Q�n�A>L�Z�V�Fv�~��.�y�ϧ&�S�X�9UjB�V�Q�5�,6�M��i�z��,�8�X8����b0N�@NS� BI8����b��O�w�ʃa���q�9�G�4�҇#xDn��Š����=" ��^q1�G��z�`��G��_9�G�4�Ri�ԕ8��͑Q���x�dAV��d�ΑQ•=,�F����?�"�x�c�1!�ku�����L"|p��W#����kauv`#���phD��ȸ�\��tEM#���ҿ1�z�wq&q��za�/-����7d���#� �p�eI��`��k! 0000043697 00000 n 0000047142 00000 n 0000044401 00000 n 0000040831 00000 n ChemInform Abstract: Highly Efficient and Selective Photocatalytic Hydrogenation of Functionalized Nitrobenzenes. Simple, rapid, clean and environmentally benign synthesis of aromatic nitro compounds by using inorganic nitrates as nitrating agents adsorbed on silica gel as a solid support has been reported. 0000057668 00000 n endobj Oxygenated carbon species contribute to the formation of CO2 and might be involved in the formation of isocyanates. Nitro compounds are organic compounds that contain one or more nitro functional groups (−NO2). %%EOF Compounds 11, 20, and 24 bound to the translocator protein 18 kDa (TSPO) in submicromolar range using [(3)H] PK-11195 binding affinity assay. 0000047389 00000 n 0000041087 00000 n Download & View Aromatic Nitro Compounds.pdf as PDF for free. 0000044143 00000 n 0 0000035449 00000 n 0000044172 00000 n Nitration 2.1. 0000019002 00000 n chemoselectivity without affecting other sensitive functional groups. 0000015331 00000 n of deposits on the catalyst was considerably lower for propane. 8 0 obj xref

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