Number of times cited according to CrossRef: Combined XPS and contact angle studies of flat and rough ethylene‐vinyl acetate copolymer films. 81 (1989) 145-156, Sumarokova T.N. Pro.Prir.Rastv.Termod.Svo.Rastvorov (1989) 23-27, Wanchoo R.K.; Narayan J.; Raina G.K.; Rattan V.K. 206 0 obj <>stream Sensitivity varies, with most people having a perception threshold around 120 mg/L. The global ethyl acetate market was valued at $3.3 billion in 2018.[7]. [4][6] The combined annual production in 1985 of Japan, North America, and Europe was about 400,000 tonnes. For more data or any further information please search the DDB or contact DDBST. The data represent a small sub list of all available data in the Dortmund Data Bank. The data represent a small sub list of all available data in the Dortmund Data Bank. Severe overexposure may cause weakness, drowsiness, and unconsciousness. Overexposure to ethyl acetate may cause irritation of the eyes, nose, and throat. Sigma-Aldrich Products are sold exclusively through Sigma-Aldrich, Inc. Ethyl acetate is present in alcoholic drinks, cereal crops, radishes, fruit juices, beer, wine, and spirits. The aroma of ethyl acetate is most vivid in younger wines and contributes towards the general perception of "fruitiness" in the wine. Relationship Between Surface Energy and Surface Contamination, https://doi.org/10.1002/app.1978.070221216. [9] For example, it is commonly used to clean circuit boards and in some nail varnish removers (acetone is also used). The LD50 for rats is 5620 mg/kg,[13] indicating low toxicity. This reaction gives ethanol and sodium acetate, which is unreactive toward ethanol: Under anhydrous conditions, strong bases induce the Claisen condensation to give ethyl acetoacetate:[12]. Ethyl acetate (systematically ethyl ethanoate, commonly abbreviated EtOAc, ETAC or EA) is the organic compound with the formula CH3−COO−CH2−CH3, simplified to C4H8O2. Ethyl acetate hydrolyses to give acetic acid and ethanol. 29 (1952) 313-317. Ethyl acetate, also know as ethyl ethanoate, or acetic acid ethyl ester, consists of four carbon atoms, eight hydrogen atoms, and two oxygen atom. In the lab, ethyl acetate is a universal solvent for column and thin-layer chromatography. J.Org.Chem. Name Molecular Formula CAS# Mol. Pressure-Temperature Calculator for Solvents, © 2020  Merck KGaA, Darmstadt, Germany and/or its affiliates. Reproduction of any materials from the site is strictly forbidden without permission. III. All Rights Reserved. Enter your email address below and we will send you your username, If the address matches an existing account you will receive an email with instructions to retrieve your username, By continuing to browse this site, you agree to its use of cookies as described in our, I have read and accept the Wiley Online Library Terms and Conditions of Use. Combined XPS and contact angle studies of ethylene vinyl acetate and polyvinyl acetate blends. [16], Except where otherwise noted, data are given for materials in their, National Institute for Occupational Safety and Health, Ullmann's Encyclopedia of Industrial Chemistry, "Ethyl Acetate: A Techno-Commercial Profile", "Ethyl Acetate Market Share 2019 | Industry Report, 2027", "Copper and Secondary Amine-Catalyzed Pyridine Synthesis from, https://pubchem.ncbi.nlm.nih.gov/compound/ethyl_acetate#section=Toxicity, National Pollutant Inventory – Ethyl acetate fact sheet, Purpose of Using Concentrated Sulfuric Acid in Esterification for Catalysis, A Techno Commercial Profile of Ethyl Acetate in India, https://en.wikipedia.org/w/index.php?title=Ethyl_acetate&oldid=982349435, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, This page was last edited on 7 October 2020, at 16:14. Surface‐free energy analysis of hydrolyzed ethylene‐vinyl acetate copolymers. It is most widely commercially synthesized via the Fischer esterification reaction. Step-by-step solution: Site Use Terms Ethyl acetate hydrolyses to give acetic acid and ethanol. �'6�3?$�p�`��Hp3p��Ҍ@� � .RU] Ethyl acetate is only weakly Lewis basic. Ethyl acetate is a polar aprotic solvent. In perfumes, it evaporates quickly, leaving only the scent of the perfume on the skin. Ghani NA, Sairi NA, Aroua MK, Alias Y, Yusoff R (2014) Density, surface tension, and viscosity of ionic liquids (1-ethyl-3-methylimidazolium diethylphosphate and 1, 3-dimethylimidazolium dimethylphosphate) aqueous ternary ; Jr.: Parachor Studies at Various Temperatures. [4], Ethyl acetate was first synthesised by Count de Lauraguais in 1759 by distilling a mixture of ethanol and acetic acid. endstream endobj startxref J.Am.Oil Chem.Soc. h޼W�o�8�W�}E�G���B*��k��q������.�IRi���;'�i���cf~?�0�JX�haFBˉP g�(ʡM�N��d�AVT� UK�G�>��9���4��)�p�� ��iJU(H"�0���d\6~yJ��1w+:Q���܌N4n�������>�'��[�LV���f���C��f�����y�H���y�ɷ�G�ӓ]�bn7�. it is very good. ��X'Z0pOp����n0MI���~|���T.ۇ��,���0�1�``H��5���c�J:A The liquid density at this temperature is 0.90063g/cc. Because it is not hygroscopic, ethyl acetate also keeps the insect soft enough to allow proper mounting suitable for a collection. ; Clemens M.L. The full text of this article hosted at iucr.org is unavailable due to technical difficulties. Ethyl acetate results from the reaction between ethanol and acetic acid. h�b```f``R �\�� ���� Abstract Ethylene‐vinyl acetate copolymers containing 4, 11, and 19 wt.

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