P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/\u2026if you feel unwell. 1338-23-4) SDS. For precautions see section 2.2. Vigorous decomp can be stimulated by even trace amt of a wide variety of contaminants, such as strong acids, bases, metals, metal alloys and salts, sulfur cmpd, amines, accelerators or reducing agents. [3] Later studies found that a linear dimer is the most prevalent in the mixture of products typically obtained,[4] and this is the form that is typically quoted in the commercially available material from chemical supply companies.[5]. CAS No: 1338-23-4; Molecular Weight: 210.226; Molecular Formula: C 8 H 18 O 6; Names and Identifiers Properties Safety and Handling NMR Spectrum Computational chemical data 51 Suppliers The Register: Mass murder in the skies: was the plot feasible? 2-[(2-Hydroperoxybutan-2-yl)peroxy]butane-2-peroxol, InChI=1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3, Except where otherwise noted, data are given for materials in their, National Institute for Occupational Safety and Health, Institute for Occupational Safety and Health, CDC - NIOSH Pocket Guide to Chemical Hazards. Oxidizing/reducing agents,Process regulators, 8F, Block C, No.3 Building, Zijin Plaza, No.701, Gudun Road, Hangzhou, Zhejiang 310030, China. Methyl ethyl ketone peroxide (MEKP) is an organic peroxide, a high explosive similar to acetone peroxide. Wear self-contained breathing apparatus for firefighting if necessary. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Combustible LiquidCombustible. SECTION 13 - DISPOSAL CONSIDERATIONS Limited information is available on the chronic (long-term) effects of methyl ethyl ketone in humans. P411 Store at temperatures not exceeding \u2026\u00b0C/\u2026\u00b0F. Use personal protective equipment. According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low. MEKP is a severe skin irritant and can cause progressive corrosive damage or blindness. P260 Do not breathe dust/fume/gas/mist/vapours/spray. UNSTABLE AGENT WHICH LIKE HYDROGEN PEROXIDE RELEASES OXYGEN. No smoking. An estimated BCF of 13 was calculated for the 2-butanone peroxide mixture(SRC), using an estimated log Kow of 2(1) and a regression-derived equation(2). Do NOT induce vomiting. New York Times: Details Emerge in British Terror Case, The Free Information Society: HMTD Synthesis, How MEKP cures Unsaturated Polyester Resin (video animation), https://en.wikipedia.org/w/index.php?title=Methyl_ethyl_ketone_peroxide&oldid=981778377, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, This page was last edited on 4 October 2020, at 11:21. Sweepings may be placed in open containers or polyethylene bags and the area washed with water and detergent. Incompatible with strong oxidizing agents, strong reducing agents, natural rubbers, synthetic rubbers and chemical accelerators. Fresh air, rest. Remove contact lenses, if present and easy to do. Recommended Exposure Limit: Ceiling Value: 0.2 ppm (1.5 mg/cu m). Explosive decomposition occurs at 110\u00b0C. Extremely destructive to tissue of the mucous membranes, upper respiratory tract, eyes, and skin. Personal protection: chemical protection suit including self-contained breathing apparatus. Refer for medical attention . Do not discharge to sewer systems. According to a classification scheme(2), this estimated Koc range suggests that some portions of the 2-butanone peroxide mixture are expected to have very high mobility in soil, whereas other portions of the mixture are expected to be essentially immobile. This is particularly true of methyl ethyl ketone and benzoyl peroxides, which are intentionally stimulated to decomp @ room temp using small amt of accelerators. Continue rinsing. P280 Wear protective gloves/protective clothing/eye protection/face protection. In the case of eye contact, the eyes should be flushed immediately with large amounts of water, and medical attention should be obtained. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. 2-Butanone peroxide is a strong oxidizing agent(3) and may decompose when brought in contact with organic materials(SRC). Synonym: 2-Butanone peroxide solution, Methyl ethyl ketone peroxide solution Linear Formula: C 2 H 5 C(OOH)(CH 3 )OOC(OOH)(CH 3 )C 2 H 5 Molecular Weight: 210.22 Ignition and/or explosion may occur if mixed with readily oxidizable materials. ... Medical attention should also be obtained in case of accidental ingestion. Synonyms & Trade Names. ... /Peroxides, Organic and Inorganic/, In case of fire, water should be applied by the sprinkler system or by hose from a safe distance, preferably with a fog nozzle. Benzoyl peroxide can be used for the same purpose. Ignition and/or explosion may occur if mixed with readily oxidizable materials. The first to be reported was a cyclic dimer, C8H16O4, in 1906. P363 Wash contaminated clothing before reuse. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Portable extinguishers should not be used except for very small fires. Chemical degradation is expected to be the dominant fate process in water because of reaction with organic matter and therefore, it is doubtful that un-reacted 2-butanone peroxide would be biologically available(SRC).

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