Any queries (other than missing content) should be directed to the corresponding author for the article. Kinetics and pathways of selective hydrogenation of 1-(4-nitrobenzyl)-1,2,4-triazole. Light absorption in the Rh nanocrystals generates hot electrons that are injected into nitrobenzene molecules adsorbed on the Rh surface, accelerating the reduction of nitrobenzene and favoring the transfer coupling of reduced nitrobenzene intermediates into azoxybenzene. Xinyan Dai. Nguen Tkhi Tkhu Kha, O. V. Lefedova, A. Light‐Driven Dry Reforming of Methane on Metal Catalysts. ChemInform Abstract: Selective Catalytic Hydrogenation of Nitrobenzene to Hydrazobenzene.. Selective catalytic hydrogenation of nitrobenzene to hydrazobenzene. Highly efficient synthesis of aromatic azos catalyzed by unsupported ultra-thin Pt nanowires. and you may need to create a new Wiley Online Library account. Lei Hu, Xueqin Cao, Liang Chen, Junwei Zheng, Jianmei Lu, Xuhui Sun, Hongwei Gu. Highly Selective Synthesis of Hydrazoarenes from Nitroarenes via Polystyrene-Supported Au-Nanoparticle-Catalyzed Reduction: Application to Azoarenes, Aminoarenes, and 4,4′-Diaminobiaryls. Verhoeven, Y.-K. Sun. Citations are the number of other articles citing this article, calculated by Crossref and updated daily. You may need to download version 2.0 now from the Chrome Web Store. You have to login with your ACS ID befor you can login with your Mendeley account. 12 publications. The large size of silica particles also improves the colloidal stability of the small Rh nanocrystals, benefiting the photocatalytic performance. Orella, A.L. You’ve supercharged your research process with ACS and Mendeley! The initial reaction rates for the hydrogenation of nitrobenzene (r 1), nitrosobenzene (r 2), and azoxybenzene (r 3) were determined to be 0.34, … Find more information on the Altmetric Attention Score and how the score is calculated. Number of times cited according to CrossRef: Promoting reactivity of photoexcited hot electrons in small-sized plasmonic metal nanoparticles that are supported on dielectric nanospheres. Working off-campus? Completing the CAPTCHA proves you are a human and gives you temporary access to the web property. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Qiuwen Liu, Yan Xu, Xiaoqing Qiu, Caijin Huang, Min Liu. Please check your email for instructions on resetting your password. Learn more. Yasuhiro Shiraishi, Miyu Katayama, Masaki Hashimoto, Takayuki Hirai. This article is cited by Note: Your IP: 192.151.147.66 Learn about our remote access options, Department of Chemistry, Temple University, 1901 North 13th Street, Philadelphia, Pennsylvania, 19122 USA. Chemoselective hydrogenation of nitrobenzenes activated with tuned Au/h-BN. Selective Transfer Coupling of Nitrobenzene to Azoxybenzene on Rh Nanoparticle Catalyst Promoted by Photoexcited Hot Electrons. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. The full text of this article hosted at iucr.org is unavailable due to technical difficulties. A. C. LeBlond, J. Wang, R.D. Kinetics of the hydrogenation of a mixture of nitrobenzene and azoxybenzene on skeletal nickel in an aqueous solution of propan-2-ol. Forman, F.P. Features of the kinetics of 4-nitroaniline and azoxybenzene hydrogenation in 2-propanol aqueous solutions. Use the link below to share a full-text version of this article with your friends and colleagues. To understand why azoxybenzene was the predominant product, we performed several kinetic experiments . Another way to prevent getting this page in the future is to use Privacy Pass. Parametric study of temperature distribution in plasmon-assisted photocatalysis. Highly Dispersed RuOOH Nanoparticles on Silica Spheres: An Efficient Photothermal Catalyst for Selective Aerobic Oxidation of Benzyl Alcohol. Chun-Ching Chiang, Ming-Jen Cheng, Hung-Yi Huang, Hsun-Shuo Chang, Chyi-Jia Wang, and Ih-Sheng Chen. The reaction rate and product selectivity of nitrobenzene reduction catalyzed on Rh nanocrystals of several nanometers in size are significantly improved under illumination of visible light.

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